The Ocean Plays A Deeper Game

Around 19,000 years ago, oceanic conditions underwent dramatic changes that coincided with a shift in global climate, marking the onset of the Holocene warming. In the North Atlantic, major changes in the Meridional Overturning Circulation (MOC), which carries warm and highly saline surface water north to cooler regions, played a substantial role in regulating climate and levels of atmospheric carbon dioxide. Scientists are now convinced that the ocean absorbed, stored, and released vast quantities of carbon in the past, playing a major role in the end of the last Pleistocene Ice Age glacial period. Understanding the ocean's role in the past is important to understanding how it may influence climate in the future. A new report in Science shows that the MOC experienced a series of abrupt changes that lasted from decades to centuries, and may have stored and released more CO2 than previously thought.

It is beginning to look like the Atlantic ocean's overturning current flow has had a very active and varied history during the last deglaciation, 18,000-10,000 years ago. Two articles in the January 14, 2011, issue of the journal Science explain the latest discoveries about the part ocean circulation in the Atlantic has played in climate change. Reporting in a perspective article, “Northern Meltwater Pulses, CO2, and Changes in Atlantic Convection,” Professor Michael Sarnthein, a researcher in Paleoclimatology and Paleoceanography at the University of Kiel, reviews “impressive and detailed evidence of how the North Atlantic MOC behaved after the Last Glacial Maximum (LGM).” According to Sarnthein, some old oceanographic dogma needs to be changed:

Today, intensive convection in the North Atlantic quickly transfers surface waters to depth, and newly formed deep water typically has a ventilation age of ∼500 years. In contrast, Thornalley et al. report that during the Heinrich stadial 1 (HS1), a cold interval that occurred between about 17,500 and 14,700 years ago, a mass of extremely old water, up to 5200 years old, reached the Atlantic Ocean's northern “dead end.” They suggest this was intermediate water that originated in the Southern Ocean near Antarctica, and its age would once have been considered unreasonable. In addition, they found that the ventilation ages of past surface waters could vary by as much as 2100 years, which agrees with results of other methods and challenges a common, but little-substantiated dogma: that past surface waters had ventilation ages of ∼400 years, similar to a current age average.

As regular readers of this blog know, this is but the latest chapter in science's changing view of the MOC (see “Conveyor Belt Model Broken” and “Ocean Conveyor Belt Dismissed”). According to Sarnthein, such old ages and long cycling times are important because they suggest the ocean absorbed, stored, and released vast quantities of carbon in the past. Furthermore, researchers can use this new information to estimate MOC and CO2 storage patterns during the LGM and HS1 (see the figure below). This new work suggest that deep waters at those times were, on average, ∼1000 to ∼2000 years older than they are today, suggesting that the ocean absorbed and stored a massive amount of atmospheric CO2 during the LGM and early HS-1. During those periods, deepwater CO2 concentrations in about half of the ocean's volume were markedly higher than today's levels.

Average apparent 14C ventilation ages and possible short-term circulation changes of ocean deep and intermediate waters during the Bølling interstadial, Heinrich stadial 1 (HS1), and the Last Glacial Maximum (LGM). Ages in blue are as low as or lower than current ages, indicating good ocean ventilation. Ages in orange are higher than current ages, and represent CO2-enriched waters. Numbers in green are 14C ages of topmost intermediate waters outside the Nordic Sea, and numbers in black are water depths (rounded). Source M. Sarnthein/Science.

The basis for these conclusions is a research paper by David J. R. Thornalley, Stephen Barker, Wallace S. Broecker, Henry Elderfield and I. Nick McCave entitled “The Deglacial Evolution of North Atlantic Deep Convection.” In it, Thoranalley et al. describe using water-column radiocarbon reconstructions to examine changes in northeast Atlantic convection since the Last Glacial Maximum. The authors explain the importance of their work:

Open-ocean deep convection in the North Atlantic occurs in the Labrador and Greenland Seas, transforming well-ventilated, nutrient-poor surface waters into North Atlantic Deep Water (NADW), which spreads southward to occupy much of the deep Atlantic. Paleoceanographic studies suggest that deep convection in the North Atlantic was altered during the last ice age as compared with today. Glacial convection was shallower, forming Glacial North Atlantic Intermediate Water (GNAIW), and possibly weaker, leading to poorer ventilation of the deep Atlantic. Rapid fluctuations between weak and strong modes of deep convection could also be linked with abrupt climate changes across the North Atlantic region because of the associated changes in the poleward flux of warm surface waters. Furthermore, mode switches in deep convection might be triggered by changes in the input of fresh water, with the Younger Dryas (YD) cold reversal being the archetypal example. Yet there is growing evidence that the YD may be part of an intrinsic oscillation associated with deglaciation, rather than peculiar to the last termination. To test these hypotheses, we require precise constraints on the timing (and rate) of deep convection changes relative to abrupt climate events and freshwater perturbations.

The main tool used for this study was analysis of 14C/ 12C ratios found in various proxy sources—planktonic and benthic foraminifera. Cosmogenic radiocarbon (14C) is produced in the upper atmosphere when cosmic rays interact with nitrogen. The 14C is taken up by the ocean through air-sea gas exchange with the levels seeking equilibrium. Over time the radioactive decay of 14C into 12C alters the ratio between the isotopes and allows determination of the apparent time elapsed since a water mass was last in equilibrium with the atmosphere. This is called the 14C ventilation age.

Through painstaking and detailed analysis, combining many data sources, Thornalley al. have built up a new and more complete picture of ocean ventilation during the end of the last glacial period and the onset of the Holocene warming. Deglacial intermediate/deep (I/D) ventilation ages show similar trends throughout the deglaciation, alternating rapidly (within ~100 to 200 years) between close-to-modern values (500 years or less) and extremely old ages (3000 to 5200 years). This implies abrupt changes in deep convection during this period.

“In general, young I/D ventilation ages are seen during warm intervals [e.g., the Bølling-Allerød (B-A) and early Holocene] and reflect the rapid transfer of equilibrated surface waters to depth, similar to today’s ocean,” the authors state. “However, the occurrence of extremely 14C-depleted waters between 1.2 and 2.3 km during cold intervals [e.g., Heinrich stadial 1 (HS1), the Intra-Allerød Cold Period (IACP), and YD] demands not only a shoaling of convection but also the incursion of a very depleted water mass that must already have been in existence.”

This implies that during cold intervals of the deglacial period, the influence of 14C-depleted Antarctic Intermediate Water (AAIW), which formed along the northern margin of the Southern Ocean, reached as far north as ~60°N in the North Atlantic, much farther than today. Today, the influence of AAIW reaches 20 to 30°N in the Atlantic Ocean. The complex and previously undocumented interaction of ocean circulation patterns with deep reservoirs of Antarctic and Arctic water hints that the ocean holds other mysteries within its depths. The figure below provides a summary view of the studies ventilation age findings.


Cartoon contour plots for the ventilation age.

One of the things bandied about by global warming alarmists is the possibility of a shutdown of the MOC, bringing a sudden cold spell to the Norther Hemisphere similar to the Younger Dryas. It has been argued by some that the Dryas shutdown was a onetime event triggered by the release of a huge volume of fresh water into the arctic ocean as a result of a glacial dam break. Thornalley et al. suggest that the timing of these events may be a bit different than conventional wisdom proposes:

A long-standing view of Northern Hemisphere deglaciation has been that the strong resumption of deep convection in the North Atlantic during the B-A was interrupted by a freshwater rerouting or flood event, which reduced convection and triggered the YD cold reversal. In contrast to this paradigm, our I/D ocean ventilation results show that after the vigorous convection of the early B-A, there was a shutdown in open-ocean deep convection in the high-latitude NE Atlantic for a sustained interval beginning ~600 years before the onset of the YD, that is, during the IACP. The occurrence of an earlier shutdown in deep convection in the NE Atlantic before the YD suggests that in terms of NE Atlantic convection, the YD was not a unique event during the deglaciation. Instead, the amplified circulation associated with the Bølling warming was probably a transient feature of deglaciation, and the stability of deep convection in the NE Atlantic gradually weakened throughout the B-A, with intervals of vigorous deep convection being punctuated by several freshwater events. This interpretation is consistent with the recent recognition of “YD equivalents” during earlier terminations of the Late Pleistocene.

This conclusion does not dismiss a freshwater release as the proximate cause for the Younger Dryas, but, rather, suggests that such events were frequent during the deglaciation. They served as aberrations causing rapid, dramatic climate changes on top of a general warming trend reflected by stability in the Atlantic circulation. Even though large variations are detected in the present day MOC, it still looks like a sudden, Dryas like cold spell requires a massive infusion of glacial melt water that could not occur today.

The significance of this work should not be underestimated. “Thornalley et al.'s findings represent real progress,” concludes Sarnthein. “For instance, their extremely old ventilation ages for intermediate and deep waters—together with other high ages—may help explain what happened during the "mystery" interval, a period of rapid decrease in atmospheric 14C that occurred 17,500 to 14,500 years ago.” While the exact mechanisms that caused the last deglaciation remain unknown, this works may help scientists to narrow down the possibilities.


Atmosphere and ocean exchange CO2 more rapidly than thought.

Additionally, it was found that the ocean holds deep reservoirs of ancient water that, under certain conditions, can shift north out of the Antarctic during cold periods. This echos findings of a Southern Ocean source for the deglacial radiocarbon-depleted CO2 detected in the eastern North Pacific (see “Southern Ocean source of 14C-depleted carbon in the North Pacific Ocean during the last deglaciation”).

In the Atlantic, this can impact currents and convection by interacting with the flow of North Atlantic Deep Water (NADW), which spreads southward to occupy much of the deep Atlantic. The resulting rapid fluctuations between weak and strong modes of deep convection causes changes in the poleward flow of warm surface waters, and that can impact sea-ice cover in the Nordic Seas.

“We have suggested that differences in the timing of changes in open-ocean convection and sea-ice coverage between the NE and NW Atlantic may be an important control on atmospheric circulation,” the authors conclude, “therefore, further investigation into the nature of the atmospheric reorganizations associated with this heterogeneity is warranted.”

It seems that when it comes to controlling Earth's climate, the ocean plays a very deep game indeed. Thornalley et al.'s work also shows that the world's oceans can release or absorb atmospheric CO2 much more rapidly that previously thought. It is the shifting of ocean currents, both on the surface and deep below, that cause Earth's temperature to fluctuate and weather patterns to change. Atmospheric CO2 doesn't control climate, the ocean controls both climate and the amount of CO2 in the air.

Be safe, enjoy the interglacial and stay skeptical.

14C/ 12C ratios

one thing i have wondered is what sort of proxy allows them to double check how much c14 is being made to accurately derive what it should be so they can get accurate ages?

cosmic radiation im doubting has been a constant over millions of years, and when your getting down to the very very small levels used for dating, even small variations in the starting level can shift dates.

Carbon dating

It always amazes me that proxy data based on miniscule amounts of carbon isotopes, which contain very significant uncertainties, get quoted as though they are solid fact. You might be interested in the paper “Timing is Everything: The Boon and Bane of 14C Geochronology,” by T.P. Guilderson, P.J. Reimer and T.A. Brown, all researchers at the LLNL Center for Accelerator Mass Spectrometry. As the authors state in the paper's abstract: “There are underappreciated limitations of the conversion of 14C-ages to the fixed, calendrical time-scale that bear directly upon our understanding of the dynamic climate system.”

The initial 14C/12C ratio is not constant with time or among Earth’s various carbon reservoirs. That being said, calibration is possible by analyzing the 14C content of items dated by independent methods. Dendrochronology (age dating by counting tree rings) has been used to calibrate 14C/12C ratios back more than 11,000 years before the present (Becker and Kromer 1993; Becker et al. 1991). Using uranium-thorium dating of corals, 14C dating has been calibrated back more than 30,000 years (Bard et al. 1990; Edwards et al. 1993), and to 45,000 yeas ago by using U-Th dates of glacial lake varve sediments (Kitagawa and van der Plicht 1998).

Finally, 14C dating has been pushed to its limit of around 50,000 years using ocean cores from the Cariaco Basin, which have been calibrated to the annual layers of the Greenland Ice Sheet (Hughen et al. 2004). Because of 14Cs relatively short half life, only 5,730 years, it is not possible to date things older than around 50,000 years before the present. Naturally, the farther back you go the more uncertainty creeps into the measurements: ±20-40 years for 0-8,000 years BP, ±hundreds for dates before that. The truth is all such data must be taken with a grain of salt.

perfect

thats exactly what i was looking for.

i found the bits about plateau periods very insteresting.

thanks

Reply to SkS

Dear Doug Hoffman

I think that you need to reply to this SkS article
http://www.skepticalscience.com/co2-warming-35-percent.htm

regarding your article
http://theresilientearth.com/?q=content/estimated-co2-warming-cut-65

Reply

My article, including the correction at the bottom, speaks for itself. I do not waste time by trolling on climate change true believer sites.

questions for Doug

Doug, can you post an answer to these questions?

1. How much CO2 was in the deep oceans when CO2 levels were highest -- in other words, what was the estimated pH of the waters when and where CO2 storage was high?

2. Assuming the pH was low, do we have any sense as to how creatures, especially cold water corals, fared?

Thanks,

John

Ocean acidification

The problem with estimating CO2 content of the ocean when atmospheric CO2 was highest is that this occurred a very long time ago—what paleontologists call deep time. There are proxy readings from various sources but the samples tend to come from limited geographical areas and have larger uncertainties. The highest Cenozoic level of atmospheric CO2 was during the PETM, around 55 million years ago. While it is true that the atmosphere and the ocean constantly try to achieve equilibrium with respect to dissolved gases, a number of factors affect this process.

CO2 solubility is affected by temperature—colder water can hold more CO2 than warm water, but atmospheric levels were highest when the oceans were much warmer than today. In general, high-latitude oceans take up CO2 from the atmosphere and tropical waters release CO2 to the atmosphere. CO2 is also about 10% higher in the deep ocean than at the surface. Both chemical and biological reactions regulate the ocean's carbon content.

Carbon in sea water takes a number of forms, both organic and inorganic dissolved carbon compounds are present. When CO2 disassociates in water it can form carbonic acid (H2CO3), the source of concern over dropping ocean pH values. But it is also acted on by biological organisms which can result in release of calcium carbonate (CaCO3), which is alkaline. Some carbon is also held in the tissues of plankton and does not contribute to the pH level unless the plankton dies and decays (which releases the carbon as CO2 again). You might find the discussion in “The Alkalinity and Total Carbon Dioxide Concentration in the World Oceans” and my previous post “Ocean CO2 Storage Revised” interesting.

That said, the IPCC AR4 report estimated that there are around 38,000 gigatons of carbon in the ocean. As for historical levels, we have no good estimates that I can find. There are estimates but they are often contradictory. The article reviewed above states that, during the recover from the PETM when CO2 levels were many times higher than today, “rapid and permanent removal of CO2 would have been an increase in ocean pH throughout the PETM, thereby contributing to supersaturation of ocean waters with respect to CaCO3 and massive carbonate deposition observed in seafloor records.” So high levels of CO2 can lead to reactions in the ocean that can result in alkalinity rather than acidity. Of course, other authorities say just the opposite.

As for the survival of ocean life, including corals, throughout Earth’s history there is evidence of large carbon dioxide releases, greenhouse conditions, and ocean acidification. For one review see “Marine Life Survived 8X Current CO2 Levels.” Some forms of sealife actually seem to do better when CO2 levels are high (see “Ocean Absorption Of CO2 Not Shrinking ”). Corals live in both deep and shallow water, under a variety of temperatures. If the ocean changes temperature some corals may die and others take their place. Earth has been much hotter than today, the seas much warmer, and corals have survived.